#10. Andrea Pirlo
This visionary from Italy is one among the best specialists of penalty shots in the world of football today. Pirlo excels at set play and has been always praised for his calmness and confidence. It has also helped him give good shots past the goalkeepers of all calibers. It was only Pirlo, who scored the first penalty for Italy in the FIFA World Cup of 2006 against France and helped his nation win the FIFA tournament. This 34-year old mastermind relies on technique instead of speed while taking his penalties. His spot kick during 2012 Euro against England can never be forgotten by the football world anytime soon.